You're correct: having a large supply does not mean that you are in a network effect business.
Tostitos has a large supply. This is not without value! It is indeed the case that a customer in search of tortilla chips can reliably get Tostitos when they might not be able to reliably get a smaller brand of tortilla chips. Tostitos is a big business that can get their brand into more stores than smaller competitors, too.
But I assume that we all agree that Tostitos is not a network effect business.
People pretty routinely confuse the advantage of "being big" (and being somehow involved with computers) with a network effect. This is bad both from a pure terminology reason (ie: we don't need a new term for "being big and somehow involved with computers," while we do need a term for actual network effects), and also in terms of confusing people about the merits of a business -- to whit, we should not assume that the rides-for-hire business is naturally going to become a monopoly because of a "network effect" when there is no network effect. In contrast, we should assume that social networks are naturally going to become monopolies because of a network effect.
Rides-for-hire-hailed-with-a-smartphone is a few things. It's a threshold business -- you need a certain density of drivers in a service area in order to offer quality of service to your passengers. If a rival of Uber can't get a certain number of drivers, they can't provide good service. But whatever that magic number is, it's also actually bad for them to have MORE drivers than that, until their passenger demand also expands. Much of the business problem of rides-for-hire is, unlike a traditional network effect business, where it's "stay bigger than your rivals," matching driver levels to passenger levels. If your number of drivers is too low, your quality of service goes down. If your number of drivers is too high, your drivers don't earn enough to continue with you, stop bothering to log in, etc.