But from a scientific perspective, both knowledge and experience arise from the physical properties of the universe; properties that predate humans and biological systems entirely. From that perspective, one could say that all knowledge is a priori.
But whether we say it's all priori or posteriori doesn't really matter. The point is that making the distinction privileges the human perspective in a way that we have no scientific evidence to support. The entire exercise begs the question by assuming that human experience is determinative, or distinct in any way from the rest of the universe.
And while I'm not totally sure about the definition of K ( specifically the whether something can be shown part), I think this would be based just on definitions, without really any axioms?
Although I suppose it is possible that I included an axiom and just wrote "Define" before it.
(tangent: I suppose one could say "define a system with the following axioms" and then make a proof about that system, and claim that it was a proof by definition?)
Maybe I don't really understand what a priori really means (this seems fairly likely) but I don't think definitions are considered a priori?
Now there are plenty of philosophers who came later who have tried instead - following in the shoes of Hume - to perform a materialist grounding of these faculties not in the brain but derived from sense experience itself - sense experience somehow constitutes the structures of the brain and changing external sense experiences can reshape or reconstitute these brain structures. For example, Gilles Deleuze seems to me to do something like this.