It's certainly a possibility, but my guess is that based on windows' pretty crazy market penetration (I don't think I've ever met anyone who's _never_ used a windows machine at least at work or school), and the fact that most switching is going the other direction (away from windows), the number of people "new to windows in general" is not worth considering.....but that's just a guess.
EDIT: I guess I'm not considering people who are just buying their first computer, and that that computer is a windows 8 machine......I would be really curious to see the numbers for OS breakdowns for "first time computer buyers", and how many of these were people who genuinely never had their own vs. adults who previously used machines owned by their parents.....I'd imagine this number is also pretty small these days....