0 and below - Freezing. Wear a warm jacket and closed toe shoes or boots.
1 - 10 - Cold. Wear an overcoat (a light one if you are used to colder weather)
10-15 - Early spring time. Long sleeves are probably in order, maybe even a sweater.
15-20 - Late spring. Wear short sleeves.
20+ - Warm to hot. Wear short sleeves. If it gets to be 24+ shorts are appropriate.
I am deliberately not giving conversions to Fahrenheit here because I think that's how you just go back to using it. Try to internalize the metric system here.
The second challenge is to switch your clocks/watches to the 24 hour mode. Not strictly metric system related, but you will not have to worry about AM vs PM again.
For the advanced users: switch your car to show your speed in km/h instead of m/h.
For the super-advanced users: try to figure out how many liters per 100 km does your car consume :).
Edit: if you cook (and you really should), use a scale set to grams instead of measuring cups for any recipes you are making. Almost all foods list both oz's and grams on them. You will get much more accurate measurements this way and will learn to gauge what 150 grams of cheese looks like, etc.