The Normal Distribution: A derivation from basic principles [pdf]
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This loosely means that if you have n samples that are independently drawn from the same distribution, their sum approaches a normal distribution for large n. The generality comes from the fact that this happens (almost) independently of distribution the samples come from.
http://en.wikipedia.org/wiki/Maximum_entropy_probability_dis...
Often, where a measurement is perturbed by a litany of physically unlinked disturbances (e.g., antenna noise), the CLT argument is compelling. In a case like antenna or front-end electronics noise, justifying the maxent argument would require buying in to an almost mystical belief by comparison.
Interestingly, the two seem to have a deep connection related to thermodynamics, e.g. http://en.wikipedia.org/wiki/Thermal_fluctuations, where you can see both as expansions of a configuration count up to second order in the exponent.
This is manifest in the detectable remnants of the Big Bang, which are a particular realization of a Gaussian random field that was present due to quantum fluctuations of a primordial system. It's funny to think of the universe as a draw from a random number generator.