Exactly.
Most utilities already do this, but they have to come out to your house to put a controller on your AC compressor, and have separate infrastructure to communicate load shedding commands to this controller.
Nest (like all startups) abstracts away this pain, while charging based on the value provided (which is enormous, considering the cost of running peaking natural gas generators when demand is at its highest).
EDIT: http://www.nj.com/business/index.ssf/2010/07/peakers_plants_...
"Peakers like the Jersey City plant are extremely expensive to maintain. However, they are considered essential to maintaining the reliability of electricity during heat waves. So, PJM has a way for power plants to be paid for keeping these plants in operation.
It costs ratepayers about $13 million annually for PSEG to keep the plant operational. That cost could vary depending upon how many days of the year PJM decides the plant is available to operate. The more days it’s available, the higher the charge to ratepayers."
My opinion: Intelligent load shedding through Nest-like operations, along with the dramatic increase in wind and distributed solar generation, is going to do away with peaker plants.