An overhaul of the battery will jump-start a shift to renewable energy
theatlantic.com
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Battery science is hard, capacities are limited by chemistry, and the easy-to-find electrolytes (also the cheapest and most abundant) are fairly well known. Barring breakthroughs in allotropes (such as graphene, everyone's current favorite carbon molecule), novel inorganic molecules, or biotech-derived approaches, I suspect chemistry doesn't have a whole lot extra to give us. Even reasonably abundant minerals such as lithium portent supply crunches when scaled to, say, a century or more worth of battery EV production (though Elon Musk speaks confidently of addressing this via recycling -- though no recycling process is 100% efficient).
The more interesting approaches I've seen for grid-scale battery storage involve possibly less efficient, and certainly less convenient, but cheap and highly abundant materials such as the molten salt or liquid metal (see Donald Sadoway's work) concepts. The chemistry works, the materials abundance is there.
I've played with some back-of-the-envelope calculations suggesting that for electrical energy storage, very large scale thermal storage, say enough for two weeks of supply at the scale of the US, is plausible. The heat-substrate facility would be approximately the size of an existing very large petroleum storage tank farm (these exist in Oklahoma at the terminus of several oil pipelines). See: http://redd.it/1viied
But the really useful forms of energy storage humans have turned to are long-chain hydrocarbons, whether created recently in nature as olive oil, beeswax, tallow, or other biogenic oils, or in the form of petroleum, and to a lesser extent gas and coal.
The prospect of the US Naval Research Lab's electricity-to-fuel project utilizing seawater as a source of both hydrogen and CO2 to feed a Fischer-Tropsch synthesis process strikes me as among the most promising prospects I've read in a long time. It requires an external energy supply (the Navy proposes existing nuclear reactors aboard aircraft carriers, or renewable energy in the form of ocean thermal energy conversion (OTEC). Proposed at a scale of 100,000 gallons of aviation fuel (essentially kerosene or diesel) daily, fed by 240MW of electrical energy (roughly the scale of a carrier's reactors), at a cost of $3-$6 per gallon of fuel produced, it's more expensive than present fossil fuel energy sources, but, when tied to a renewable energy source, offers the prospect of a constant-cost liquid fuel source effectively forever.
It also seems to me that scaling this to roughly national levels of production is at least plausible. The NRL's proposal is 1/8400th of present US petroleum consumption, but scaling up costs and plant estimates, $8 trillion in capital, 2 TWe in energy, and a total of 10 m x 4.5 km x 4.5 km processing facility volume, would replace the 20 million barrels of oil presently consumed daily in the US. This compares against some $4 trillion in capital expenditures on new conventional petroleum exploration from 2005 - 2012 with a net reduction in oil supply of 2 million barrels/day.[1] And yes, the supplied electrical energy is an additional cost: this won't be cheap. But it's forever.
Round-trip efficiency isn't great: no better than the 60% efficiency of hydrogen electrolysis, with additional energy input requirements for CO2 extraction and a lot of seawater handling (8.8 billion liters/day for the Navy's proposal, 74 trillion at national scale). But once produced, oil doesn't suffer from the relatively rapid storage losses of most alternatives: a few percent per hour or day for many battery, thermal, or kinetic flywheel systems. If used for electrical generation there's another 30% generating loss experienced, for a maximum net efficiency of 42%, but if used to provide liquid fuels to critical uses, this could well prove highly attractive -- there are somethings it's really hard to substitute for.
The process should also be carbon neutral, though it does involve a net transfer from present ocean to present atmospheric carbon reservoirs.
I discuss this more here: http://redd.it/22k71x
It's not that I don't expect some improvement in battery technology, but there's a 5x advantage in energy storage densities (MJ/kg) between the best present battery storage technologies (lithium-air) and liquid hydrocarbons. That's closer to 25x for LiON vs. oil[2]. While incremental efficiency improvements (and better energy scavenging through, say pervasive PV surfaces) might be useful for electronics and their Moore's Law dynamics, for devices operating in the physical world and its constraints, batteries will continue to be at a disadvantage in cost, capacity, complexity, and/or abundance.
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Notes:
1. Steven Kopits presentation, February, 2014. http://energypolicy.columbia.edu/events-calendar/global-oil-... Also discussed and analyzed by Gail Tverberg: http://ourfiniteworld.com/2011/03/03/steven-kopits-oil-the-e...
A partial list of people working on it:
* Amyris
* Solazyme
* KiOR
* Algenol
* Sapphire
* Aurora
* Synthetic Genomics
* Cellana
* PetroSun
Notably, most of the companies on that list have taken hundreds of millions of dollars from domestic and foreign oil companies hoping to create their own supply. Maybe more notably, several of the companies on the list went public, then lost 80-90% of their market cap. Most are pursuing other, higher value products as a first-order business, with promises of biofuels down the road.
Remember that the transition from wood to coal occurred largely because the world was running out of wood. Otherwise, wood had a lot to commend itself: it was locally available (coal comes from limited locations), doesn't involve mining dangers, and is easier to burn (some early coal proponents in the US were accused of fraud when the "rocks" they sold wouldn't burn in existing ovens -- anthracite coal is tough to ignite).
Where opportunistic feedstocks exist, I suspect biofuels may supply some energy, but it's going to be a very small fraction of existing fossil consumption in advanced nations.
There have been some interesting developments in biofuels lately with Algenol peaking above >10,000 gallons/acre/year rate and demonstrating a sustained rate north of 8,000 gallons/acre/year. There have been some murmurs of breakthroughs in genetically modifying the photosynthesis pathway as well, which could have a dramatic affect on per-acre productivity.
Is that algenol productivity associated with open-air production, or is that in an artificial controlled environment with UV lighting and a highly engineered grow space?
Even if those production rates can be sustained, you're looking at 30 million acres for algae cultivation.
Technical details are thin, but I've found their 9kgal/acre-yr release:
http://www.biofuelsdigest.com/bdigest/2013/03/11/algenol-hit...
If you manage to build some of the infrastructure in the oceans, the area doesn't even matter (that doesn't mean it would be easy, there is just lots of room).
A few hundred miles on a side is the size of many larger states in the US, and that assumes a 100% fill factor. Add in requirements for access roads, equipment, human habitations and support, and that's going to increase, though I'm not sure by how much -- 10% to 30% wouldn't surprise me.
Built as a corridor, 30 million acres is 1000 miles x 47 miles -- an assembly of grow tanks stretching 25 miles on either side of an highway running from Chicago to Denver. Though more likely it would be situated in a desert region (so as not to compete with existing agriculture), but where it would compete with alternative direct electrical (or electricity-to-fuel) alternatives.
Even if the area doesn't require freshwater access, it will require water, and for that to be transported (likelihood of occupying thousands of miles of coastline are slim) considerable distances inland, and then back out again (waste streams and salt). All of which are both capital and operationally intensive.
Building sea-based structures would similarly be insanely capital intensive. You'd be better off finding a way to create an inland salt lake (say: in the Dead Sea or Death Valley) and situate your grow-ponds there.
Marine or even simply salt-water environments are very, very harsh and hard on structures (even concrete) and equipment.
You can also put some of those acres in other places, you don't have to take them all from Texas.
You're constrained by alternative land uses, requirements for sunlight, avoiding freezing (even in Texas and California, desert regions see frosts), and access to seawater.
Elsewhere in the world you could situate grow ponds in warm desert regions: the Sahara, northern and western Australia, the Arabian peninsula (somewhat ironically, requires more comic san(d)s), and similar areas, though these would be among the largest.
The world uses 100 million barrels of petroleum daily, the US about 20 million (slightly less). Even small uses of petroleum such as aviation (about 2% of the total) represent vast amounts of fuel. And with projected population and energy utilization growth, demand will increase above this.
The basic maths are laid out in a paper I've found to be a tremendously useful reference, Jeffrey Dukes, "Burning Buried Sunshine": http://globalecology.stanford.edu/DGE/Dukes/Dukes_ClimChange...
Briefly: present human consumption of net primary productivity (plant growth) is about 14% of Earth's total. The fossil fuels consumed in 1997 (the date analyzed by the paper) comprise the equivalent of another 21% of NPP (and the actual period over which the fossil fuels accumulated is far greater: 400 years of growth, accumulated over ~5 million years, due to inefficiencies in the process of coal, oil, and gas formation and accumulation).
You can look at biofuels on an energy per unit area basis. There's roughly 1 KW/m^2 of incident sunlight. Current PV solar cells convert around 20% of this, and tend to capture the equivalent of 8 hours of sunlight per day, which is to say, a 30% capacity factor. Maximum PV efficiency (with far higher costs of production) is around 85%. But with present commercially available means, you can capture 20% of 1 kW for 8 hours each day, or roughly 1.6 kWh per day. A kilowatt (kW) is a unit of power, a kilowatt-hour is a unit of energy.
US electrical production of roughly 4,000 TWh would require 7800 km^2 of area to produce, or a square 88 km on a side.
That's for electricity.
Plants and algae have an efficiency of from 1-10%, with conventional crops and plants generally in the 1-3% range. We can do the same area calculation as above, or work from yields expressed as gallons of fuel per acre. A high-yield crop such as canola is generally given as 100 gal/acre, hemp advocates claim as much as 300 gal/acre (though this is generally disputed), and algae biofuels as much as 1000 gal/acre.
Given the 7.3 billion barrels of oil consumed, lets work out acreage requirements for algae. GNU Units is one of my favorite tools for this:
You have: 7.3 billion barrels / (1000 gallons/acre)
You want: million km^2
* 1.2407662
That is, we need 1.24 million km^2, or a square 1113 km on a side (that's 479,000 mi^2, or a square 692 miles on a side, or a bit more than 300 million acres of land.There are presently slightly more than 400 million acres of land under agricultural production in the US. Three quarters of that would have to go to fuel production under one of the most productive biofuel processes we have.
Moreover, algae require ponds, which is to say, a LOT of water, pumping pesticide, fertilizer, and a lot of processing.
Say you figured out a way to move all of this off-shore, and could set up grow-ponds in the oceans off the Atlantic and Pacific coasts? They're roughly 1000 miles long each, so to figure on the width of our algae grow structure, we divide 479,000 by 2000 and find ... the ponds would have to extend only 239 miles off-shore. That's from Key West, FL, to Eastport, ME, from San Diego, CA, to Port Angeles, WA. And they'd have to survive freezing and nor'easters and hurricanes and ...
Yeah, sounds kinda tough.
If the US population and per-capita energy utilization were far less, say maybe 10% of present levels, this might be conceivable, but as things stand, not really. And then there's the rest of the world.
Even more modest proposals to, say, supply aviation fuel from halophyte + aquaponics farms, described by Boeing as the biggest breakthrough in biofuels, really doesn't add up: http://redd.it/1wo2hl
(Another interesting fact I discovered in researching that was that the US hit Peak Aviation Fuel in 1999, and present flight activity is more than 30% below what projections of that time suggested. Passenger miles are up somewhat given increased load factors -- more bumped flights and less legroom due to cramming more people onto fewer flights. Kopits points this out also in his presentation, confirming my observations.)
Which is why I find the NRL's project so interesting. The magnitude of its plant and scale requirements is far, far less than competing biofuel alternatives.
Reading about that is probably one of only two positive things I've read about in the last decade. The other being birthrates dropping in the US and elsewhere.
What I particularly like about the US NRL research is (pardon if I'm repeating myself):
• It's based on two very well-established technologies: hydrogen electrolysis and the Fischer-Tropsch process. I suspect other power-to-gas processes are based on this or similar (Sabatier process,
• The novel techology is reasonably minor: CO2 extraction from seawater. Much of the research involves improving the efficacy of this process.
• It addresses the feedstock challenge: CO2 content of seawater is relatively large.
• It is a good match for sustainable energy sources, both base-load (geothermal) and intermittent / variable (solar, wind, tidal).
• It produces well-understood liquid hydrocarbons for which we have considerable experience in utilization.
• Costs and scale appear reasonable.
• It appears highly sustainable.
Dropping birthrates is indeed another positive, though that's got to move far further.
Electrifying rail is certainly possible and it's the mode under which much European freight rail operates. The challenge for other regions: the US, Canada, Russia, China, and Australia in particular, is that distances are far greater, meaning far more km to energize. There's also existing traction (railroad engines) which would have to be replaced. The costs are not insignificant, though I'd really like to see long-term plans.
Electrifying drayage (that is, non-fixed-track overland cargo) is a significantly different prospect. The advantages of trucking over rail are both spatial and temporal flexibility: trucks can go anywhere there are paved roads (and some places there aren't), and don't generally need to wait for tracks to clear or switching points to move. This is at a cost of much, much higher costs expressed as dollars per ton-mile.
If you're going to fully electrify trucking, you've either got to fully electrify every mile on which trucks travel, and there's vastly more road mileage than track, or you've got to provide for some level of local energy storage on the truck. That storage has to be able to re-charge quickly, provide sufficient energy to meet transport demands, not impose excessive weight and space demands, and offer high price/performance characteristics.
The usual suspects all have some pretty significant issues: batteries, flywheels, capacitors, etc. Not that it's impossible, but being able to dump a few hundred gallons of long-chain hydrocarbons in a tank and use them as needed has major benefits.
Then there are other off-the-grid uses, though most of these tend to be a relatively small fraction of current petroleum use: small equipment (from chainsaws and leaf blowers to mowers and tractors), construction equipment, ag use, remote power (generators, etc.), shipping (electrifying the oceans would be a significant engineering challenge), aircraft (ditto skies), etc. Even where many of the specific instances might be substituted otherwise, there are current edge cases (and in the case of general aviation, pretty much the whole case) which are really predicated on liquid hydrocarbons. Not to mention industrial processes reliant on petroleum/fossil inputs (chemicals, plastics, steel)
In noting that it's plausible for all existing petroleum utilization to be substituted by synthesis, I'm not saying that it's either necessary or desirable. I do see much present petroleum use being substituted, likely by direct electric power + storage (batteries do work for many instances).
But if you can swap out all of it, then the prospect of substituting smaller portions of utilization, say at the order of 5-25%, is also feasible. And that gets you a long way.
He is much more credible when he simply quotes Stephen Chu. That much better batteries would change the world is not controversial. Actually making it happen is the tricky bit.
[1] https://www.theatlantic.com/past/docs/issues/89may/fallows.h...
To me it's exactly the opposite. Fallows isn't infallible, but his opinions are always measured and carefully-considered. For probably 30 years now I've been interested in what he's had to say about any variety of issues (except his interest in beer, which strikes me as perhaps an affectation calculated to present an Everyman image).
For example, Fallows moved to Japan in the 1980s, living and working there for several years if memory serves. His view on Japan's economic future was extremely widely held back then; many, many smart people have scratched their heads since then, wondering why things didn't go as predicted. (Who'd have thought it: History not unfolding as predicted; now there's something new, eh?)
As to Fallows's views on China, he has been a voice of moderation --- again in part because he moved there to live and work for a few years.
The combination of electrochemical systems, with mechanical requirements make the tradeoffs subtle and the gains sometimes elusive.
Ex: We tested some new SLA(Sealed Lead Acid) batteries that claimed 20% improvement. They provided very close to that number. But they were totally unacceptable for us - the plates were too fragile and were breaking/shorting in transit.
And no, that would obviate the benefits of their new technology.
Existing grids have benefited from the fact that though any given individual demand rate might vary widely, averaged over a large number of consumers, trends are far more predictable.
On the generating side this hasn't typically been as much of an issue, with highly reliable and dispatchable generating plants. With intermittent renewable/sustainable sources, the fact that local variations in solar or wind capacity can be mitigate by transmitting surpluses, or importing necessary capacity, also helps. In an advanced grid with attached storage, again, large-number averaging should, with effective management, help balance supply and demand.
Trying to do this at the scale of individual households means far more variability which must be dealt with on he immediate premises. This is among the reasons I strongly doubt that visions of a "gridless future" will emerge, at least so long as there's not widespread collapse of all social and technical infrastructure.
http://www.theatlantic.com/technology/archive/2013/11/the-10...