Unfortunately with the Snowden disclosures, there isn't much that I rule out of bounds for the NSA when it comes to things critical to internet security. OpenSSL is so widely used and critical, it would be silly to think that it would escape scrutiny by the NSA.
For example of NSA efforts in related areas (which I figured you would already know): http://www.cnbc.com/id/101301261 http://nation.time.com/2013/11/04/google-shocked-the-nsa-hac... http://www.reuters.com/article/2014/03/31/us-usa-security-ns... https://www.techdirt.com/articles/20130909/11430124454/john-...