- pgsql supports synchronous master-slave replication natively, with excellent performance
- mysql supposedly does multi-master replication, but does not solve the hard problems. You can't write on the same row on two masters simultaneously or replication stops; sequential ids are not synchronized between masters; you can't get serial transaction isolation between masters.
All in all, I'd rate replication support between both databases as nearly identical. Pgsql does master-slave better, mysql has a half-hearted attempt at multi master. Given that on all else pgsql is markedly better, I can't see replication as the reason for picking mysql.
We may have too much clueless developer in the wild, imitating for security.
Like the more linux is spreading, the more the sect of the post devil spread, you recognize them with their dark incatation: chmod 777 (the number of the post devil) and chown root:root.