1. Pick the node with the highest degree 2. Make all the connections for that node until it has a value of zero by connecting it with the highest-value node that it isn't already connected to
For example, in this scenario: http://i.imgur.com/O8MlWzz.png
The way that I see it is that since the highest-degree node needs to make X number of connections, ensure it can make all of those connections before worrying about anything else. In this case, that means start by connecting the 4 to the next highest value node - the 3, then the 2, then the other 2, then the 1.
This leaves the following situation: http://i.imgur.com/9vZjafr.png
It's kind of easy to see where it goes from there. Sure this is a simple example, but as I said it's worked 100% of the time I've tried it.