For starters, the incredibly dangerous runkit extension (like importing Objective-C's runtime).
There's also the Reflection API, which provides introspection and is quite widely used.
PHP also has magic methods, such as __call(), which give the ability to handle calling a method that doesn't exist.
As others have mentioned about Objective-C, these are all nice tools to know about and understand, however using them is often a code smell and can lead to unmaintainable code.
PHP doesn't have anything like categories, which is a shame because they look really useful in cases (as long as you don't mind violating the SRP a little). PHP has traits, which are more similar to mixins in ruby than categories in Objective-C.
Oh, PHP also has eval().