They run their PHP on HHVM for one:
https://en.m.wikipedia.org/wiki/HipHop_for_PHP
https://github.com/facebook/hhvm
...and yeah, it executes PHP code, for sure. But right there, things are already different, and the reality is that they've written a substantial code base in C/C++.
And, two, I'm sure they retain some serious business proprietary trade secrets about their server infrastructure, meaning that while the web front-end might render out HTML like a souped-up CDN, behind the scenes, there is a shit ton of other stuff going down.
Honestly, I think they just leave the file name extensions in the URL for the sake of nostalgia.