It's not an animation, but when I saw the visual illustration of eigenvalues/eigenvectors on this page I was blown away:
http://en.wikipedia.org/wiki/Eigenvalues_and_eigenvectors
I studied linear algebra in college and computed plenty of eigenvalues/eigenvectors, but until I saw that graphic I had no idea what they actually were. I can't believe in retrospect that a textbook would explain them without an illustration like this.