No, the point of a minefield is to funnel attackers into predefined areas where you've arranged to bring your heavy weapons, specifically artillery or machine guns, to bear with best effect. These areas rejoice in the name "killing zones", and their purpose is to maximize the effect of said heavy weapons by concentrating their targets in a single compact mass which can be saturated with fire. Granted, being a static emplacement, a minefield can only be effective when someone has to go through it or find a way around it; that said, and while the point is certainly arguable, I have a hard time considering a weapon, whose sole purpose is to make it as easy as possible to slaughter one's opponents en masse, as being particularly "defensive".
Not when you throw them at someone.