The thing about chemistry, is people who aren't chemists think its all about randomly mixing solutions, so the more chemicals the better.
The actual metric for doing interesting reactions is the number of tools, measurement devices, and apparatus you have. The actual chemicals are almost secondary.
I really enjoyed my undergrad quant class. So a "kit" that would entertain me would involve a ridiculously precision balance / scale, and a spectrophotometer, and a chemistry desiccant / dehydrator vessel thingy and several burettes and graduated cylinders. And the usual array of glassware. Vacuum sep funnel, distillation set, that kind of thing. Oh and I got a huge kick out of electrochemical machinery, I mean at least a precision pH meter but more advanced stuff would be cool. I'm not asking for an NMR or a FTIR spectrometer but who knows what a devoted makerspace could pull off.
Given that kind of gear listed above, I could find chemicals laying around a perfectly normal kitchen or basement to entertain me.
Number and type of chemical is a bad metric. Its like saying the best CPU to program on is the one with the largest instruction set, so a IBM360 is precisely exactly 9.1244 times "better" than a PDP-8. Well it just doesn't work that way. On the other hand a metric of tools and apparatus actually is a pretty good metric.