That only applies if you are actually experiencing hunger. I've been doing intermittent fasting for a couple of years and I haven't been hungry one single day - I don't even remember what it feels like. I eat once a day, usually at the end of the day.
It's well known that natural level of catecholamines (adrenaline, noradrenaline) are raised during the fast. As a result, most intermittent fasters report increased focus and alertness during this period. This article about ghrelin is yet another piece of the puzzle of why IF works so well for some people.