> considering that the sellers might be cops
Why wouldn't law enforcement pose as buyers, as well? This is a common tactic in narcotics enforcement. Entrapment often isn't an issue, as the seller took the first step of advertising the drugs for sale.
Are you getting at the fact that the buyer must have a receiving address, while the seller can ship anonymously? I would be skeptical of that. If I were attempting to track the source of a package, and I had the full force of warrants behind me, I bet I could track down most shippers.
Every shipping company has its own tracking information. Much of this may be opaque to the end user. The tracking might be much more detailed than what you can see as an end user with a tracking number. Assuming the carrier cooperates with law enforcement, tracking could (presumably) be further enhanced for targeted post offices, routes, etc..
For example, suppose I, as a law enforcement agent, receive an order from a Silk Road seller. Let's say it was shipped in an envelope, dropped off at a USPS street-corner box. From the tracking info, I identify which post office first handled the envelope. Thus I narrow my search to a few possible mailboxes served by that post office.
I instruct the carriers at that post office to assist me. As they follow their routes, emptying mailboxes, I have them sort outgoing mail into separate bags, one per box. I have the post office flag any mail going to my address.
I place another order from the same seller. When it hits the post office, it gets flagged, and because of the per-box sorting, I know which mailbox was used.
For round three, I place yet another order, this time with the mailbox under surveillance. I also install a camera inside the mailbox that sees the destination address of every envelope deposited. When the seller drops his shipment, my surveillance team detects it. They then follow the person who dropped the letter. Now I have the shipper's identity.
Can these measures be defeated with appropriate opsec? Maybe, if you know exactly what tactics law enforcement will employ. But you don't. You could spend all your time defending against the tactics I just described, only to get caught because law enforcement came up with a totally different strategy.
My point is, opsec is really, really hard.