Specifically cat urine, not other urine? I must be thankfully smell-deficient because I wouldn't be able to tell the difference, and I grew up with cats for 20 years
It's similar for smoking - nonsmokers can easily identify traces of smoke smell (like, this particular jacket was worn recently to a place where people smoked) that are not noticeable by the smoker itself.
If we had two sets of items, one of which we had some cats pee on, and one of which we had some humans pee on, you think you could sort them into cat/human groups with a high degree of success?