SSL relies on a chain of trust, and it's prudent to assume that the NSA has the private keys necessary to produce valid certificates that will be accepted by the certificates that ship with Windows, OS X, Firefox, etc out of the box.
So man-in-the-middle attacks are certainly within their capability and fairly hard to detect. As to whether the NSA can passively intercept and decrypt SSL traffic, I don't know, but they may not need to.