Proving something exists nonconstructively using probability.
en.wikipedia.org
en.wikipedia.org
For a (Curry-Howard) corresponding intuition, a program is no longer functional the moment any computational effect is involved (mutable state, control effects like continuations and backtracking, etc.).
Basically the proof goes like this: Define a random variable that can only take on integer values. Show that the expected value is less than one. The random variable must therefore sometimes take on the value of zero.
If your random variable was defined to mean something interesting at zero, then the above is an existence proof. What they mean by "non-constructive" is that you still don't actually have an example of the thing existing -- you just know it does. Very cool.