C# 2 added generics (courtesy of the same people that did F#) and closures (albeit with syntax as verbose as JS).
C# 3 added LINQ, which is a major breakthrough for end-users, although I'm not fond of the query language. So really, C# 3 just added in some basic features you expect from proper languages. I do understand this required a huge amount of work, esp. with the tooling required.
C# 4 added dynamic (F# provides ? operator you can provide your own implementation for, if you really feel that strings look ugly). Oh, and it finally backpedalled on the no optional parameters (although the optional parameters is the same broken C-style callsite implementation).
C# 5 added async (F# had a more flexible implementation 6 years before).
What else? C# seems to have stagnated, although I understand that's a feature for some of their users. C# still lacks type inference in most places, making it extra verbose. C# expression trees are still very limited. C# still can't easily do tuples. Not sure they deserve a break; this was MS's "flagship" language.
OTOH, The CLR itself doesn't seem to be getting any upgrades, either - IL stayed locked at v2. It's as if they realised they have done better than the JVM can ever do (generics via erasure just sucks) so why bother pushing it further?