The quality of work is often different as well, in my case it's more of a pushing to get things done at any costs, without refinement or nuance.
BTW- If you google "caffiene brain blood flow" you'll find out that it reduces blood flow to the brain by 20%. That can't be good...
... if you're a preterm infant
But what I really want to say is that what you're saying doesn't work in the long run. If you never drink coffee, it can be used as drug to help concentrate. But when drinking it daily, as the article states, your body will adjust and now you need coffee just to get to the old level without coffee.
It's the only thing that matters to the person in question.
If you mean "matters" as in allows you to gain knowledge about what actually happened to you? Then it means nothing, from whichever perspective you care to choose.
Another thing that works for me is formulating a plan of action before I have any coffee, and then drinking it when I start. The caffeine and the ritual put me in the right mindset to get real work done.