Nobody that I know buys 5-liter tins of oil (I'm italian) and I wouldn't even know where to buy them. The most common format is 1 liter, followed by 0.75
Most households in Greece will have something like that, and they're easy to find in any country if you go to a Turkish, Greek, or Arab supermarket. I could be wrong about Italy.
It varies by country, but heating doesn't necessarily exclude an oil from "extra-virgin olive oil"; the separate "cold-pressed" label covers that.