Pinned tabs are not included in any benchmarks I've seen but have a drastic positive impact on memory usage and speed. I typically have 20 or so pinned tabs and only 1-3 unpinned tabs when I quit Firefox. A cold start takes just a few seconds and about the only time I restart the browser is when I restart my system (2-3x per week).
Chrome loads all tabs on start so it can take around a minute to load the same 21-23 tabs. And furthermore Chrome tends to operate sluggishly after a couple hours of use with so many open tabs, so when using Chrome I tend to close then reopen the browser every couple hours.
Chrome 5 had a similar feature called phantom tabs but it was removed in Chrome 6. I loved that feature and was very unhappy when it was removed.