I'm working on the client-side (Chrome) and my knowledge in the server area is therefore limited, but from my understanding this would be really hard.
1. Googlers have access to almost all source code. It would be difficult to hide code that just sends data to an outside entity.
2. Google continually monitors its (internal) bandwidth. This is done to optimize traffic, and detect intruders. A rogue Googler would trigger the same traps that are exist for potential hackers.
3. Google's infrastructure changes. You can't just install a gateway to the NSA and expect it to continue working for a long time. It's not as if user-data was stored in simple text-files.