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If it's going over the wire, you can bet they have access to it, with or without 'access.'

Facebook is opt-in https and I believe google is https by default. I don't know about the other services.

Without their keys having it over the wire won't get them what they want.

EDIT: poor wording.

I don't think it's a stretch to think the government has the ssl keys. Or the ability to find the ssl keys.