I can see several reasons for this:
1 - Build a database of short to unshortened URLs as a backup in case that one of the shortening services goes under.
2 - Such a service can be useful for anyone who wants to know where the URL points to without clicking it (or without the skills to unshorten it themselves).
3 - It could allow for batch unshortening
4 - A database can still unshorten URLs that no longer exist etc..