1 - http://imagine.gsfc.nasa.gov/docs/ask_astro/answers/980301b....
1 - http://imagine.gsfc.nasa.gov/docs/ask_astro/answers/980301b....
Vacuum isn't. It is a terrible conductor of heat. So bad, that after 15 minutes a very small battery powered pen camera started to red on the edges of the video: it was starting to heat up! The only way to cool off is via radiation, which takes quite a while. If you had a large array of very conductive, high surface area material, then you could get cold. But our skin isn't like that. Rather, it's wet and insulative. The membranes that are wet immediately suffer evaporative cooling, but once frozen will have to sublime to cool any more, which is slow. The skin is dead on the outside and has layers of insulation in the form of water and fat.
No, the research, testing, and industrial accident reports show that you die from oxygen deprivation. (And you can find vacuum labeled as an asphyxiate, since inhaling it is deadly...)
EDIT: I should note that the temperature of the vacuum really is very low. That's not disputable. But there just aren't enough atoms in a vacuum for it to feel cold. It's one of those times our intuition about units sort of sets us up for failure: temperature is an average kinetic energy of each particle, and normally there are enough particles to matter. In a vacuum there usually aren't. (I'm lying of course: high energy plasmas can definitely heat something up given a few hours.)
As stated in the linked article:
"If we put a thermometer in darkest space, with absolutely nothing around, it would first have to cool off. This might take a very very long time. Once it cooled off, it would read 2.7 Kelvin."
So, the vacuum really is the main concern. You'd be long dead before you start getting cold.
Also, I have covered a vacuum flange with my hand. Heckuva hickie, but otherwise harmless. Smarts a bit with a dash of bruising, but the skin holds up remarkably well.
If you have a perfectly empty box (with total vacuum inside) and the walls have some temperature (for example 2.7K) then, after a while, inside the box will appear the electromagnetic field with the blackbody radiation of the walls temperature.
It's convenient to assign properties to the electromagnetic field, in this case the temperature. And the correct temperature of the electromagnetic field inside the box is the same as the temperature of the walls.
And the best thing is that the walls are not necessary! You can assign a temperature to the universe background radiation. If the distribution of frequencies of the electromagnetic field is equal to the blackbody radiation of a 2.7K blackbody, then you can think that the temperature of the electromagnetic field is also 2.7K.
More details: http://en.wikipedia.org/wiki/Photon_gas