In short, three big differences:
1. Identifiers are email addresses, not strange URI things, which is good because users are already comfortable with emails identifying them.
2. Privacy: Your OpenID provider can see what services you log into. Not true with Personas, which was a big deal for Mozilla and for me.
3. Browser integration: The APIs are currently implemented with a javascript shim, but the browser can step in (either via native support or an extension) to provide new, exciting types of authentication -- dongles, certificates, interpretive dance via a kinect, etc.