What if a developer is most productive using Bazaar, Fossil, Monotone, or perhaps Arch?
You might as well ask, "What if a developer is most productive using cvs?"
A change resulting in a short-term loss of comfort and productivity can lead to a long-term increase in productivity and equal comfort, but everyone who's used to something likes to think it's a global optimum instead of merely a local optimum. There is also benefit in using the same tools that other developers use when collaborating on a project.
If your name is Git, you're number 1 in the DVCS space. If your name is Mercurial, you're a distant 2. If your name is neither of them, only a few people have ever heard of you. Sort of like this: http://xkcd.com/435/