The reasons to upgrade to Python 3 are both numerous and serious. If the only hit on your code base is to change "print this" to "print(this)", by all means upgrade. And most conversions are automated -- just run a script named "2to3":
http://docs.python.org/2/library/2to3.html
Asking why one would want to move from Python 2 to Python 3 is like asking how much a boat costs -- if you have to ask, you can't afford the consequences. Here are some of the reasons:
http://wiki.python.org/moin/Python2orPython3
A quote: "At the time of writing (July 4, 2010), the final 2.7 release is out, with a statement of extended support for this end-of-life release. The 2.x branch will see no new major releases after that. 3.x is under active development and has already seen stable releases, such as the recent 3.2. This means that all recent standard library improvements, for example, are only available in Python 3.x."
A more complete list of the changes:
http://docs.python.org/3/whatsnew/3.0.html
Bottom line -- if you don't migrate to Python 3, over time the corner you're painting yourself into will become smaller and smaller.