- DoS
- Disclosing of sensitive files (in general, the XML has to "validate". In PHP, it's always possible to read any file accessible by the process parsing the XML).
- Making arbitrary network connections (with this an attacker can portscan a network, attack vulnerable services that would be protected by firewall, and/or use the vulnerable server as a restricted kind of proxy).
- Probing LDAP directories.
- Remote code execution.
See, for instance:
http://media.blackhat.com/bh-us-12/Briefings/Polyakov/BH_US_...
http://defcon.org.ua/data/2/2_Vorontsov_XXE.pdf
http://www.insinuator.net/2013/01/rails-yaml/
Edit: As a clarification, I'm not implying that any of the above (apart from the DoS issue) is applicable to Django. I'm just saying what can possibly happen (and often happens for PHP apps).
On some Windows systems, you can use a UNC path (\\share) and force the parser to try and connect to a share that the attacker controls, which will cause windows to hand over the user's hash during the handshake.