> Who made this decision
Nobody. Going back to 1989 every AOL account had a screen name that was used as your login and your identity. Being an employee was just a flag on your account in the database.
In 1993 AOL launched its internet gateway that accepted something@aol.com and put it in your AOL Mail box. You could tell that someone was an AOL employee because a banner (I think it was) appeared at the top of the message telling you.
Some of the network engineering folks had real aol.net addresses, but I don't know how that was handled internally. I also think the Netscape folks eventually made enough of a stink to keep their previous email address too.