There is no tax rate < 100% that discourages a higher income.
In a nutshell, "High top marginal personal income tax rates are found to impede long-run productivity". Source on this is OECD, but original PDF link no longer works http://www.cato.org/blog/oecd-admits-high-personal-corporate...
The tax brackets are known to everyone, including those who pay the salaries - if you want to get someone to do that 20% extra work, and they'll want a 20% increase in net pay, then you can just do the math and pay the appropriate gross.