10kwh x 100 x 24 = 24,000kwh Solar panels nominaly produce 1000kwh/m so 24,000m2 of panels... if facing the sun perfectly during normal day/night cycles. But non-equator latitudes need far more land than that because the sun isnt directly overhead, plus winter/rainy days... it is a massive solar farm (and a massive battery) just to replace an average highway gas station.
Given that any future 2-lane highway might see a couple thousand thousand EVs each hour, each needing charging every couple hundred miles, the number and size of solar charging stations per mile is crazy.