“Org” in this context is emacs org mode. Seems odd in this day and age that anyone would see hierarchical text format and think “regex”!
The two are useful for different layers of abstraction: regex is for lexing and PEG is for parsing.
Speaking of the Chomsky hierarchy, last I checked, it is still unproven whether or not PEGs can parse all context free languages. Intuitively, they're _probably_ weaker than CFGs, but no one has yet provided a counter example.