A long standing interview question I've used is "draw us an ERD for this domain" (orders/customer/products).
It's what at first is a seemingly simple question to start drilling into understanding of systems "so if I was going to do X, what would you change in your ERD?" "how about if scenario Z was going to happen, would you change anything?"
Strange how every now and then you get a "system architect" that can't answer that one.