Won't a nuclear winter kill 100% of humans? Or runaway climate change (5+ degrees)? Or do you think some people in bunkers will live through these events?
Volcanic eruptions occasionally inject literally cubic kilometres of stuff high into the atmosphere. That’s insufficient to cause a global winter, only a year without a summer: https://en.wikipedia.org/wiki/Year_Without_a_Summer
And we’ve already exploded many hundreds of nuclear weapons and no nuclear winter.