Ironically P.o.d. didn't really use MMX at all except for Dolby Surround decoding[1].
Doesn't look like there's any conclusive info out there, so probably someone needs to actually decompile it and look for MMX opcodes.
The remaining references available regarding this factoid are incredibly ancient, too:
- https://groups.google.com/g/comp.sys.ibm.pc.games.misc/c/MRF...
- https://www.mobygames.com/game/644/pod/user-review/2384353/
No idea if any additional support was added in one of the subsequent releases.