Nested functions have a different ABI from regular C functions, due to the invisible static chain register that needs to be set up. C has no way of indicating this different ABI, so GCC happily lets you cast a nested function to a C function pointer by creating a little tiny function that puts the right value in the static chain register before calling the nested function. This little tiny function is the trampoline.
Since the trampoline needs to live somewhere, GCC puts it on the stack, requiring the stack to be executable and consequently a whole lot of people hate the feature because it's a walking security nightmare.