I was involved in a project that made such a twin for a warehouse. It was simpler in theory because there was no manufacturing process. Just moving objects from one place to another. It was still expensive and took a long time. We tracked traffic heatmap but also collected data on and modelled luminosity for safety. On top of that there was a standard warehouse space optimization.
You're going to run into similar problems as with testing and documenting code. Eventually something will change - a process, a machine, a sensor. You have to stay on top of things and update your model too. Otherwise they will drift apart and not be as useful.
Meanwhile having a separate copy of the plant is also not often viable, once the plants get to any kind of size.
edit: After having 'someone' fact check and remind me: there are quite a number of simulation tools available that can sometimes partially do the work.
But a decent LLM should be able to translate the description of a plant to a TLA+ model (or Alloy, or something similar.)
Small plants in the middle of nowhere, especially municipal ones? You're lucky if it was designed this century and not 50-100 years ago. Everyone's just trying to keep old stuff running at absolute minimum cost.