You are dismissing my point, then asking me to make it.
You can think of tests/measurements of values as falling into different classes. The strongest tests of all are for the critical values of systems. Because any discrepancy would result in entirely different system behaviors.
Single highly accurate measurements are much lower on the rung. Complementing those are many tests with known statistical inaccuracy. Etc.
Single tests? Every experiment involving quantum mechanics tests pi's role in those equations to a much lesser extent. Similarly, any test involving gravity tests the gravitational constant. But we have much stronger tests for pi in quantum mechanics that we do for g in gravitation.
There isn't just one kind of measurement/test, there are many. And we want the strongest test we can make in any given situation.
But of course, we can always perform weaker tests.
Validating pi in quantum mechanics can be done with extreme robustness, because the entire theory depends on that value critically. Even the tiniest discrepancy would result in different physics compounding over all Plank space and time units, over billions of years and universe expansion, and we wouldn't be here.
Of course, we can't rule out any discrepancy. But in this case, we can rule out discrepancies down to unimaginable infinitesimals. I doubt anyone even knows how to characterize how much of a discrepancy from pi would still be consistent with what we know. That tiny.
The criticality is what gives us this far stronger test. Non-critical values cannot be tested this way. Pi can. Particular tiny ranges of stable constants in a stable 3-body system can (to a lesser extent, given the smaller system and higher bounds on criticality).
Another way to view the systemic criticality of pi, is to recognize that pi is not just a representation for a particular magnitude, but a representation of conserved cyclic behavior. Any deviation from pi breaks cyclic behavior. Thus, the implications of pi in a theory, and our ability to test pi, are profoundly greater than for most other constants. Because the difference between cyclic vs. non-cyclic behaviors, is profound. Not just slightly different behavior, but entirely different behavior.