"Simulating explosions helps determine maintenance for nuclear warheads?"Yes. Radioactive material is, by definition, slowly becoming non-radioactive by decaying into other atoms. You can think of those other atoms as 'contaminants' in your plutonium soup.
What this means is if you create a nuclear warhead, and put it on the shelf, if you did nothing you would have a very sophisticated box holding some lead. But long before that it stops working as a nuclear warhead.
So what you do is you take put one on the shelf in the lab and you sample it periodically to see how its content has changed, and run your simulations to see if plutonium or uranium with those makeups would still work within the boundaries of the device, and you try to test it periodically under conditions that simulate, as much as possible, an actual explosion.
They used to do this at the test site, basically explode one warhead from a batch every 2 - 3 years to insure they still worked. But they stopped when we banned such testing.