Email currently uses an HTTP request to https://mta-sts.<domain>/.well-known/mta-sts.txt, per RFC 8461. Depending on HTTPS/TLS instead of DNSSEC is one major reason you see this approach gaining popularity.
I might add that if you want to enforce SMTP TLS, you can do just that without mta-sts or DANE.
What concerns do you have with MTA-STS?