At one point I got scared by the prospect that I might be an expert on Postgres on AWS, because frankly I didn't know all that much about it and thought we were doomed if that was really the case.
Then I went over had lunch with the Heroku team, and it was eye opening. These guys truly knew how to run Postgres on AWS (and presumably still do).
I can't think of another org that is moving Postgres on AWS forward better than Heroku.