I'm the original/lead developer of Ardour, a cross-platform DAW, and have been working with digital audio for more than 25 years.
There are no 32 bit ADCs - your SD MixPre's are giving you (at best) 22 bits packaged as a 32 bit float value. The preamps make absolutely zero difference to the AD conversion (though they might sound real nice).
> Surely you understand a recording made at 48kHz has a max freq response of 24kHz and played at half speed that max freq is 12kHz
This is a very naive version of what "played at half speed" might actually mean. If properly and correctly resampled, this is not true.
> And when I load a 192kHz recording to izotope RX I can literallu see the harmonics going up to 96kHz
Well, I'd certainly hope so! But the question is: what are the energy levels associated with the partials above Nyquist? If you recorded at 384kHz with sensitive enough equipment, you'd see partials above 96kHz - but at extremely low energies because ... well, that's just how physics works.
[EDITED to remove AD/DA confusion]