Peak performance happens at peak power draw and is a matter of having as much hardware as possible pushing as many operations as possible at any given point without spontaneously combusting. Those who have the most advanced manufacturing process, or architecture with the most execution units and best able to keep all units busy wins.
Peak power efficiency is about being able to turn as much hardware off as possible, and having lower quiescent current ("leakage power"), with bigger, beefier chips naturally having higher quiescent currents.
What is talked about here is about gating hardware such that you can shave off milliwatts or microwatts when the system is completely idle, by taking tasks that otherwise use slightly larger blocks that would have to remain on and moving them to smaller, more dedicated blocks. For example, being able to play a video with most render capabilities powered down because the display server can take the output of a hardware video decoder block and feed it straight into a display controller plane.