In the back of my mind, I find it oddly surprising that we have 3D printers but I haven't seen a printer where you can mix your own pigments and print with them.
Many years ago I knew someone in Seattle who made microprints with burnished copper plates, some of them with a dozen different colors. He designed a couple of commemorative postage stamp-like objects, and that somehow got him hired by an eastern european country as an anti-counterfeiting advisor and then he disappeared.