No, they need to ditch drive letters first. The NT kernel and NTFS don't even require them (I used to mount disks without drive letters back in the NT 4 era). They just don't care enough to get rid of this annoyance.
I used to support a group of completely tech illiterate users in construction & manufacturing. Them figuring out T:\ was hard enough, ask them to type in a UNC path into the address bar in explorer and you get "Wtf is file explorer? Wtf is an address bar? Where is the backslash key??"