As someone with full-height windows at home — depending on your climate (continental Europe here, so similar to NYC or Boston, with below freezing in the winter and 40C/104F in the summer) — might not work too well. You lose space for shelves and such, opening a window can let the rain in, floor will get very cold, and depending on the glass type, you either get it to be like a greenhouse/too hot in the summer, or not leveraging the same effect in the autumn/winter. In general, on sunny days air can get stuffy even in the winter.
It can also be too bright for some types of work during sunny days — especially if facing East or West and the sun is low. All of this depends on the orientation too, and facing north it is probably perfect.
They are otherwise beautiful and have many pros: but I wanted to warn of some practical drawbacks too.